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Beilstein J. Org. Chem. 2019, 15, 2287–2303, doi:10.3762/bjoc.15.221
Graphical Abstract
Figure 1: Jablonski-type diagram displaying the classical one-photon excited fluorescence (left), and the les...
Figure 2: Two ways to represent schematized structures of dendrimers, showing the different generations (laye...
Scheme 1: Synthesis of phosphorhydrazone dendrimers, from the core to generation 2. Generation 1 dendrimers w...
Scheme 2: Full structure of the generation 1 dendrimer bearing 12 blue-emitting TPA fluorophores on the surfa...
Figure 3: Linear structure of the generation 2 dendrimer bearing 24 green-emitting TPA fluorophores on the su...
Scheme 3: Synthesis of the dioxaborine-functionalized dendrimer of generation 4.
Figure 4: Diverse structures of multistilbazole compounds, and graph of the σ2max/εmax response, depending on...
Figure 5: Nile Red derivatives: monomer (M) and two generations of dendrimers.
Scheme 4: Dumbbell-like dendrimers (third generation) having one TPA fluorophore at the core, and ammonium te...
Scheme 5: Another example of dumbbell-like dendrimers having one TPA fluorophore at the core, and P(S)Cl2 or ...
Scheme 6: The 12 steps needed to synthesize a sophisticated TPA fluorophore, to be used as branches of dendri...
Scheme 7: Synthesis of dendrimers having TPA fluorophores as branches and water-solubilizing functions on the...
Figure 6: Other types of dendrimers having TPA fluorophores as branches and water-solubilizing functions on t...
Figure 7: Generations 0, 1, and 2 of dumbbell-like dendrimers having one fluorophore at the core and either 1...
Figure 8: Double layer fluorescent dendrimer.
Figure 9: Dumbbell-like dendrimer used for two-photon imaging of the blood vessels of a living rat olfactory ...
Figure 10: Fluorescent gold complex having high antiproliferative activities against different tumor cell line...
Figure 11: A fluorescent water-soluble dendrimer, applicable for two-photon photodynamic therapy and imaging.
Figure 12: Schematization of the different types of TPA fluorescent phosphorus dendrimers and dendritic struct...
Beilstein J. Org. Chem. 2011, 7, 1577–1583, doi:10.3762/bjoc.7.186
Scheme 1: Synthesis of functionalized phenols. Reagents and conditions: a) Boc2O, 1.0 equiv, THF, 0 °C → rt, ...
Scheme 2: Single substitution of hexachlorocyclotriphosphazene. Reagents and conditions: a) Cs2CO3, 1.67 equi...
Scheme 3: Synthesis of dansylated dendrons. Reagents and conditions: a) Cs2CO3, 11 equiv, THF, rt, 48 h. b) Cs...
Scheme 4: Synthesis of dabsylated dendrons. Reagents and conditions: a) Cs2CO3, 11 equiv, THF, rt, 48 h. b) T...
Figure 1: UV–vis spectra of compounds 8–10.
Figure 2: UV–vis spectra of compounds 4, 11 and 12 in dioxane.
Figure 3: Excitation (left) and emission (right) spectra of compounds 8–10 in 1,4-dioxane (the excitation spe...
Figure 4: Emission spectra (λexc = 347 nm) of compound 10 in mixtures water/dioxane with different molar frac...
Figure 5: λem,max of 10 in mixture water/dioxane vs molar fraction of water in dioxane (filled squares) and v...